Chuck Versus the Seduction (S02E02)

Chuck goes undercover to pluck an important device from toxic spy the Black Widow (Melinda Clarke). But to penetrate her web, he must first learn the fine art of seduction from suave superspy Roan Montgomery (John Larroquette), whose best days are likely behind him. Elsewhere, Morgan provides unlikely romantic advice to Captain Awesome; and Lester adapts to his new position at Buy More. (National Broadcasting Company (NBC))